Beilstein J. Nanotechnol.2016,7, 1447–1453, doi:10.3762/bjnano.7.136
harsh conditions.
Keywords: adsorption; magnetic nanoparticles; organic pollutants; phosphonatedpolyethylenimine; Introduction
During the last decades, an increased emphasis was placed on the issue of diffuse contamination of water. Toxic metals and organic pollutants are significant sources of
successfully tested on both [15]. In addition, they often adsorb a limited amount of contaminant, considerably lower than the capacity of activated charcoal.
We report herein a new adsorption process for water remediation, based on partially phosphonatedpolyethylenimine (PEIP)-coated magnetic nanoparticles
.
Preparation of the phosphonatedpolyethylenimine–maghemite material
Synthesis of nanoparticles
Maghemite ionic ferrofluid ([Fe] = 10−2 mol/L) was prepared by wet alkaline coprecipitation according to the Massart protocol [18][19]. Iron(III) chloride and iron(II) chloride were co-precipitated at a molar ratio
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Figure 1:
Synthesis of NP-PEIP. The number of phosphonates depends on the number of equivalents of phosphorou...